Search results for "Spin system"

Pulse EPR methods for studying chemical and biological samples containing transition metals

2006

This review discusses the application of pulse EPR to the characterization of disordered systems, with an emphasis on samples containing transition metals. Electron nuclear double-resonance (ENDOR), electron-spin-echo envelope-modulation (ESEEM), and double electron-electron resonance (DEER) methodologies are outlined. The theory of field modulation is outlined, and its application is illustrated with DEER experiments. The simulation of powder spectra in EPR is discussed, and strategies for optimization are given. The implementation of this armory of techniques is demonstrated on a rich variety of chemical systems: several porphyrin derivatives that are found in proteins and used as model s…

Master equation approach to the three-state open Majorana model

2019

The three-state Majorana model in the presence of dissipation is considered. Different models of system-environment interaction are explored, ranging from a situation where dissipation is the main effect to regimes where dephasing is mainly produced. It is shown that the detrimental effects of the noise are stronger in the presence of dissipation than in the presence of dephasing. The role of temperature is also discussed.

Geometric phases and criticality in spin systems

2006

A general formalism of the relation between geometric phases produced by circularly evolving interacting spin systems and their criticality behavior is presented. This opens up the way for the use of geometric phases as a tool to study regions of criticality without having to undergo a quantum phase transition. As a concrete example a spin-1/2 chain with XY interactions is presented and the corresponding geometric phases are analyzed. The generalization of these results to the case of an arbitrary spin system provides an explanation for the existence of such a relation.

Complete Spectral Analysis of the1H NMR 16-Spin System of β-Pinene

1997

The complete analysis of the 1H NMR spectrum of β-pinene, (1S)-(-)-6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane, which is of the ABCDEFGHIJX3Y3 type, is reported and earlier results are corrected. The vicinal coupling constants, 3J(H,H), are compared with the theoretical values calculated by using the Altona and co-workers’ equations for the structure derived by molecular modelling. The results were applied to the conformational analysis of β-pinene. © 1997 John Wiley & Sons, Ltd.

Double-quantum nutations in a two-level spin system

1986

The transient oscillatory behavior of the nonlinear response of a two-level electron-spin system is experimentally investigated in a sample of glassy silica with ${E}_{1}^{\mathcal{'}}$ centers (S=(1/2)) at microwave frequency at T=4.2 K. The transient regime, excited by an intense step-modulated radiation tuned to double-quantum (DQ) resonance, is monitored by revealing the second-harmonic (SH) wave radiated by the spins undergoing DQ transitions. Time- and frequency-domain results show that the emitted SH wave has two components: the former, which vanishes at the DQ resonance, exhibits an overdamped transient regime, the latter consists of damped oscillations at a frequency which depends …

Dynamical behavior of a XX central spin model through Bethe ansatz techniques

2009

Non-Markovian dynamics of a single electron spin coupled to a nuclear spin bath

2008

We apply the time-convolutionless (TCL) projection operator technique to the model of a central spin which is coupled to a spin bath via nonuniform Heisenberg interaction. The second-order results of the TCL method for the coherences and populations of the central spin are determined analytically and compared with numerical simulations of the full von Neumann equation of the total system. The TCL approach is found to yield an excellent approximation in the strong field regime for the description of both the short-time dynamics and the long time behavior.

Competition of Direct and Indirect Sources of Thermal Entanglement in a spin star network

2017

A spin star system consisting of three peripheral two-state systems and a central one is considered, with the peripheral spins assumed to interact with each other, as well as with the central one. It is shown that such two couplings, each one being a thermal entanglement source, can significantly compete in the formation of quantum correlations in the thermal state, to the point that they can destroy any thermal entanglement of the peripheral spins.

Coupling-assisted Landau-Majorana-Stückelberg-Zener transition in a system of two interacting spin qubits

2019

We analyse a system of two interacting spin-qubits subjected to a Landau-Majorana-Stuckelberg-Zener (LMSZ) ramp. We prove that LMSZ transitions of the two spin-qubits are possible without an external transverse static field since its role is played by the coupling between the spin-qubits. We show how such a physical effect could be exploited to estimate the strength of the interaction between the two spin-qubits and to generate entangled states of the system by appropriately setting the slope of the ramp. Moreover, the study of effects of the coupling parameters on the time-behaviour of the entanglement is reported. Finally, our symmetry-based approach allows us to discuss also effects stem…

Traces of symmetry-adapted reduced density operators

1990

Formulae are derived for traces of symmetry-adapted reduced density operators in a finite-dimensional, antisymmetric and spin-adapted space. The traces are expressed in terms of traces of products of the orbital occupation number operators.